Sessler, J. L.; Jayawickramarajah, J.; Gouloumis, A.; Torres, T. as; Guldi, D. M.; Maldonado, S.; Stevenson, K. J. Synthesis and photophysics of a porphyrin–fullerene dyad assembled through Watson–Crick hydrogen bonding. Chemical Communications 2005, 1892-1894.
Abstract
A novel porphyrin–fullerene dyad assembled through Watson–Crick hydrogen bonds is described; this system undergoes photoinduced electron transfer upon irradiation with visible light to produce a charge separated state that is substantially longer lived than that of previous dyads of this type.